Rossi hotel is fine, around 10 minutes walk from train station, as Venice hotels are with stair only (no lift), most of the hotel will help client to pick up luggage to their room, but Rossi will not help, you need to move up and down the luggages to 3rd floor! If you need to check out in the morning, better to ask staff when is the best time to check up (one day before your leaving), because no receiption in the morning time, only have a madam who prepare the breakfast, open door and received payment for check out, cannot give you payment receipt and cannot pay by credit card.